Catelani, Giorgio and D’Andrea, Felicia and Guazzelli, Lorenzo and Pistarà, Venerando (2009) Toward the synthesis of fine chemicals from lactose: preparation of d-xylo and l-lyxo-aldohexos-5-ulose derivatives. Carbohydrate Research, 344/20 (6). pp. 717-724. ISSN 0008-6215
SUMMARY The transformation of (5R)-2,6-di-O-benzyl-5-C-methoxy-β-d-galactopyranosyl-(1→4)-2,3:5,6-di-O-isopropylidene-aldehydo-d-glucose dimethyl acetal (8) into partially protected derivatives of d-xylo- and l-lyxo-aldohexos-5-ulose has been reported, applying appropriate epimerisation methods to its 3′-O- and 4′-O-protected alcoholic derivatives.
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