Catelani, Giorgio and D’Andrea, Felicia and Guazzelli, Lorenzo and Pistarà, Venerando (2009) Toward the synthesis of fine chemicals from lactose: preparation of d-xylo and l-lyxo-aldohexos-5-ulose derivatives. Carbohydrate Research, 344/20 (6). pp. 717-724. ISSN 0008-6215
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Official URL: http://www.sciencedirect.com/science/journal/00086...
Abstract
SUMMARY The transformation of (5R)-2,6-di-O-benzyl-5-C-methoxy-β-d-galactopyranosyl-(1→4)-2,3:5,6-di-O-isopropylidene-aldehydo-d-glucose dimethyl acetal (8) into partially protected derivatives of d-xylo- and l-lyxo-aldohexos-5-ulose has been reported, applying appropriate epimerisation methods to its 3′-O- and 4′-O-protected alcoholic derivatives.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Lactose, D-xylo-Aldohexos-5-ulose, L-lyxo-Aldohexos-5-ulose, 1,5-Bis-glycopyranosides, Epimerization |
| Subjects: | Area03 - Scienze chimiche > CHIM/06 - Chimica organica |
| Divisions: | Dipartimenti (until 2012) > DIPARTIMENTO DI SCIENZE FARMACEUTICHE |
| Depositing User: | Prof Giorgio Catelani |
| Date Deposited: | 07 May 2009 |
| Last Modified: | 20 Dec 2010 11:52 |
| URI: | http://eprints.adm.unipi.it/id/eprint/582 |
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